Crystallographic and structural transformations of sedimentary chalcedony in flint upon heat treatment - HAL-SHS - Sciences de l'Homme et de la Société Accéder directement au contenu
Article Dans Une Revue Journal of Archaeological Science Année : 2012

Crystallographic and structural transformations of sedimentary chalcedony in flint upon heat treatment

Résumé

The early occurrence of intentional heat treatment of silica rocks has recently become a key element in the discussion about the cultural modernity of prehistoric populations. Lithic vestiges are the only sources that remain of this process and the understanding of the material's properties and transformations are essential for reconstructing the conditions and parameters applied during heat treatment. Several models of the structural transformations upon heating have been proposed in the current literature. These models are often contradictory and do not account for the most recent structural and mineralogical data on chalcedony. In order to propose a new model, we elaborated an experimental procedure and applied different techniques involving infrared spectroscopy, solid state NMR, X-ray diffraction and electron microscopy. The results show that the major transformation to happen is the loss of silanole (SiOH) and the creation of new Si-O-Si bonds according to the reaction: Si-OH HO-Si -> Si -O-Si + H2O. This reaction starts between 200 degrees C and 300 degrees C and causes an increase in the hardness of the rocks. The maximal annealing temperature and the ramp rate are the functions of the ability of the structure to evacuate newly created H2O and depend on the size of the specimen and the volume of its porosity. These results also show that the annealing duration at maximum temperature can be relatively short (<50 min) for a sufficiently large amount of transformation to be accomplished.
Fichier principal
Vignette du fichier
2012_Schmidt et al_Crystallographic and structural transformations of sedimentary chalcedony in.pdf (942.92 Ko) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)
Loading...

Dates et versions

hal-01461428 , version 1 (11-09-2019)

Identifiants

Citer

Patrick Schmidt, Sylvie Masse, Guillaume Laurent, Aneta Slodczyk, Eric Le Bourhis, et al.. Crystallographic and structural transformations of sedimentary chalcedony in flint upon heat treatment. Journal of Archaeological Science, 2012, 39 (1), pp.135-144. ⟨10.1016/j.jas.2011.09.012⟩. ⟨hal-01461428⟩
287 Consultations
172 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More