The ID21 X-ray and infrared microscopy beamline at the ESRF: status and recent applications to artistic materials
Marine Cotte
(1, 2)
,
Emeline Pouyet
(1)
,
Murielle Salomé
(1)
,
Camille Rivard
(1)
,
Wout de Nolf
(1)
,
Hiram Castillo-Michel
(1)
,
Tiphaine Fabris
(1, 3)
,
Letizia Monico
(4, 5)
,
Koen Janssens
(5)
,
Tian Wang
(6)
,
Philippe Sciau
(6)
,
Louisiane Verger
(7, 8)
,
Laurent Cormier
(8)
,
Olivier Dargaud
(7)
,
Emmanuel Brun
(9)
,
David Bugnazet
(1)
,
Barbara Fayard
(1, 10)
,
Bernhard Hesse
(1)
,
Ana-Elena Pradas del Real
(1, 11)
,
Giulia Veronesi
(12, 1)
,
Juliette Langlois
(3)
,
Nathalie Balcar
(3)
,
Yannick Vandenberghe
(3)
,
Vicente Armando Solé
(1)
,
Jérôme Kieffer
(1)
,
Ray Barrett
(1)
,
Cédric Cohen
(1)
,
Claude Cornu
(1)
,
Robert Baker
(1)
,
Eric Gagliardini
(1)
,
Emmanuel Papillon
(1)
,
Jean Susini
(1)
1
ESRF -
European Synchrotron Radiation Facility
2 LAMS - Laboratoire d'Archéologie Moléculaire et Structurale
3 C2RMF - Centre de recherche et de restauration des musées de France
4 ISTM-CNR [Perugia - Milano] - Istituto di Scienze e Tecnologie Molecolari = Institute of Molecular Science and Technologies
5 UA - University of Antwerp
6 CEMES - Centre d'élaboration de matériaux et d'études structurales
7 Cité de la céramique
8 IMPMC_PALM - Propriétés des amorphes, liquides et minéraux [IMPMC]
9 Rayonnement Synchrotron et Recherche Médicale EA 7442, Université Grenoble
10 Novitom [Grenoble]
11 ISTerre - Institut des Sciences de la Terre
12 LCBM - UMR 5249 - Laboratoire de Chimie et Biologie des Métaux
2 LAMS - Laboratoire d'Archéologie Moléculaire et Structurale
3 C2RMF - Centre de recherche et de restauration des musées de France
4 ISTM-CNR [Perugia - Milano] - Istituto di Scienze e Tecnologie Molecolari = Institute of Molecular Science and Technologies
5 UA - University of Antwerp
6 CEMES - Centre d'élaboration de matériaux et d'études structurales
7 Cité de la céramique
8 IMPMC_PALM - Propriétés des amorphes, liquides et minéraux [IMPMC]
9 Rayonnement Synchrotron et Recherche Médicale EA 7442, Université Grenoble
10 Novitom [Grenoble]
11 ISTerre - Institut des Sciences de la Terre
12 LCBM - UMR 5249 - Laboratoire de Chimie et Biologie des Métaux
Marine Cotte
- Fonction : Auteur
- PersonId : 847862
- IdHAL : marine-cotte
- ORCID : 0000-0002-4949-588X
- IdRef : 089059115
Emeline Pouyet
- Fonction : Auteur
- PersonId : 1220305
- IdHAL : emeline-pouyet
Philippe Sciau
- Fonction : Auteur
- PersonId : 18600
- IdHAL : philippe-sciau
- IdRef : 033232261
Louisiane Verger
- Fonction : Auteur
- PersonId : 738016
- IdHAL : louisiane-verger
- ORCID : 0000-0001-7616-5563
- IdRef : 193258420
Laurent Cormier
- Fonction : Auteur
- PersonId : 177070
- IdHAL : laurent-cormier
- ORCID : 0000-0002-3554-0707
- IdRef : 170528456
Emmanuel Brun
- Fonction : Auteur
- PersonId : 743042
- IdHAL : emmanuel-brun
- ORCID : 0000-0002-0332-4903
- IdRef : 191441546
Giulia Veronesi
- Fonction : Auteur
- PersonId : 737209
- IdHAL : giulia-veronesi
- ORCID : 0000-0001-9228-6082
Résumé
The ID21 beamline (European Synchrotron Radiation facility, France) is a multi micro-analytical platform combining X-ray and infrared micro-probes, for characterization of elements, species, molecular groups and crystalline structures in complex materials. Applications are mainly in the fields of cultural heritage, life science, environmental and earth sciences, materials sciences. Here, we first present the status of instruments: (i) the scanning micro-spectroscopy end-station, operating from 2.0 to 9.2 keV, under vacuum and offering cryo conditions, for the acquisition of 2D micro X-ray fluorescence (μXRF) maps, single point micro X-ray Absorption Near Edge Structure (μXANES) spectra and speciation maps with sub-micrometric resolution; (ii) the XANES full-field end-station, operating in the same vacuum and energy conditions, for the acquisition of hyper-spectral radiographs of thin concentrated samples, resulting in speciation maps with micrometric resolution and millimetric field of view; (iii) the scanning micro-X-ray diffraction (μXRD)/μXRF end-station, operating at 8.5 keV, in air, for the acquisition of 2D crystalline phase maps, with micrometric resolution; and (iv) the scanning infrared microscope, operating in the mid-infrared range for the acquisition of molecular maps and some structural maps with micrometric resolution. Recent hardware and software developments are presented, as well as new protocols for improved sample preparation of thin sections. Secondly, a review of recent applications for the study of cultural heritage is presented, illustrated by various examples: determination of the origin of the color in blue Chinese porcelains and in brown Sèvres porcelains; detection of lead in ink on Herculaneum papyri; identification and degradation of modeling materials used by Auguste Rodin and of chrome yellow pigments used by Vincent van Gogh. Cryo capabilities are illustrated by the analysis of plants exposed to chromate solutions. These examples show the variety of materials analyzed, of questions tackled, and particularly the multiple advantages of the ID21 analytical platform for the analysis of ancient and artistic materials.
Format du dépôt | Notice |
---|---|
Type de dépôt | Article dans une revue |
Titre |
en
The ID21 X-ray and infrared microscopy beamline at the ESRF: status and recent applications to artistic materials
|
Résumé |
en
The ID21 beamline (European Synchrotron Radiation facility, France) is a multi micro-analytical platform combining X-ray and infrared micro-probes, for characterization of elements, species, molecular groups and crystalline structures in complex materials. Applications are mainly in the fields of cultural heritage, life science, environmental and earth sciences, materials sciences. Here, we first present the status of instruments: (i) the scanning micro-spectroscopy end-station, operating from 2.0 to 9.2 keV, under vacuum and offering cryo conditions, for the acquisition of 2D micro X-ray fluorescence (μXRF) maps, single point micro X-ray Absorption Near Edge Structure (μXANES) spectra and speciation maps with sub-micrometric resolution; (ii) the XANES full-field end-station, operating in the same vacuum and energy conditions, for the acquisition of hyper-spectral radiographs of thin concentrated samples, resulting in speciation maps with micrometric resolution and millimetric field of view; (iii) the scanning micro-X-ray diffraction (μXRD)/μXRF end-station, operating at 8.5 keV, in air, for the acquisition of 2D crystalline phase maps, with micrometric resolution; and (iv) the scanning infrared microscope, operating in the mid-infrared range for the acquisition of molecular maps and some structural maps with micrometric resolution. Recent hardware and software developments are presented, as well as new protocols for improved sample preparation of thin sections. Secondly, a review of recent applications for the study of cultural heritage is presented, illustrated by various examples: determination of the origin of the color in blue Chinese porcelains and in brown Sèvres porcelains; detection of lead in ink on Herculaneum papyri; identification and degradation of modeling materials used by Auguste Rodin and of chrome yellow pigments used by Vincent van Gogh. Cryo capabilities are illustrated by the analysis of plants exposed to chromate solutions. These examples show the variety of materials analyzed, of questions tackled, and particularly the multiple advantages of the ID21 analytical platform for the analysis of ancient and artistic materials.
|
Auteur(s) |
Marine Cotte
1, 2
, Emeline Pouyet
1
, Murielle Salomé
1
, Camille Rivard
1
, Wout de Nolf
1
, Hiram Castillo-Michel
1
, Tiphaine Fabris
1, 3
, Letizia Monico
4, 5
, Koen Janssens
5
, Tian Wang
6
, Philippe Sciau
6
, Louisiane Verger
7, 8
, Laurent Cormier
8
, Olivier Dargaud
7
, Emmanuel Brun
9
, David Bugnazet
1
, Barbara Fayard
1, 10
, Bernhard Hesse
1
, Ana-Elena Pradas del Real
1, 11
, Giulia Veronesi
12, 1
, Juliette Langlois
3
, Nathalie Balcar
3
, Yannick Vandenberghe
3
, Vicente Armando Solé
1
, Jérôme Kieffer
1
, Ray Barrett
1
, Cédric Cohen
1
, Claude Cornu
1
, Robert Baker
1
, Eric Gagliardini
1
, Emmanuel Papillon
1
, Jean Susini
1
1
ESRF -
European Synchrotron Radiation Facility
( 2568 )
- 6 rue Jules Horowitz BP220 38043 GRENOBLE CEDEX
- France
2
LAMS -
Laboratoire d'Archéologie Moléculaire et Structurale
( 218275 )
- UPMC 4 Place Jussieu 75252 Paris Cedex 5
- France
3
C2RMF -
Centre de recherche et de restauration des musées de France
( 510 )
- Palais du Louvre 14 quai François Mitterand 75001 PARIS
- France
4
ISTM-CNR [Perugia - Milano] -
Istituto di Scienze e Tecnologie Molecolari = Institute of Molecular Science and Technologies
( 330437 )
- Milan and Perugia
- France
5
UA -
University of Antwerp
( 302250 )
- Prinsstraat 13, 2000 Antwerpen
- Belgique
6
CEMES -
Centre d'élaboration de matériaux et d'études structurales
( 460 )
- 29 Rue Jeanne Marvig - BP 94347 31055 TOULOUSE CEDEX 4
- France
7
Cité de la céramique
( 547925 )
- 2 place de la Manufacture, 92310 Sevres,
- France
8
IMPMC_PALM -
Propriétés des amorphes, liquides et minéraux [IMPMC]
( 1085141 )
- 4, place Jussieu - BC 115 - 75252 Paris Cedex 5
- France
9
Rayonnement Synchrotron et Recherche Médicale EA 7442, Université Grenoble
( 547926 )
- France
10
Novitom [Grenoble]
( 543367 )
-
Novitom – Grenoble (siège)
3 Avenue Doyen Louis Weil
F-38000 Grenoble
contact@novitom.com
Tél. +33 (0)4 28 70 23 31
- France
11
ISTerre -
Institut des Sciences de la Terre
( 1042230 )
- ISTerre, OSUG-C (Maison des Géosciences), 1381, rue de la Piscine, 38610 GIERES
ISTerre, Université Savoie Mont Blanc, Campus Scientifique, 73376 Le Bourget-du-Lac Cedex
- France
12
LCBM - UMR 5249 -
Laboratoire de Chimie et Biologie des Métaux
( 24490 )
- 17, rue des Martyrs 38054 Grenoble cedex 09
- France
|
Vulgarisation |
Non
|
Comité de lecture |
Oui
|
Audience |
Internationale
|
Date de publication |
2017
|
Volume |
32
|
Numéro |
3
|
Page/Identifiant |
477-493
|
Langue du document |
Anglais
|
Nom de la revue |
|
Domaine(s) |
|
DOI | 10.1039/C6JA00356G |
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